Formation of 2-chlorobenzylidenemalononitrile (CS riot control agent) thermal degradation products at elevated temperatures.

نویسندگان

  • Timothy A Kluchinsky
  • Michael V Sheely
  • Paul B Savage
  • Philip A Smith
چکیده

2-Chlorobenzylidenemalononitrile (CS riot control agent) has been shown to produce a number of thermal degradation products when dispersed at high temperature. We hypothesized that these CS-derived compounds are formed by energy input from heating during the dispersion process. Here we identified organic CS-derived compounds formed from purified CS subjected to temperatures ranging from 300 to 900 degrees C in an inert atmosphere with analysis of tube furnace effluent by gas chromatography and mass spectrometry. We conclude that the production of many CS-derived compounds previously observed during high-temperature dispersion is likely to be heat related.

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عنوان ژورنال:
  • Journal of chromatography. A

دوره 952 1-2  شماره 

صفحات  -

تاریخ انتشار 2002